The filter builder offers nine operators in total. Which ones appear in the operator combo depends on the type of the field you picked.
Available when the field is text (names, addresses, states).
process name excludes svchost).Wildcards are not interpreted. Type notepad to match notepad.exe, not notepad*.
Available when the field is numeric (counts, percentages, sizes, speeds, times).

and between them. The lower bound goes first; if you reverse them the filter still matches the inclusive range.Greater than or equal and less than or equal are not separate operators. To express >= 50, use greater than 49 for integers, or between with the same lower and upper bound.
Numeric operators compare in a normalized unit:
Picking a different unit in the builder's value edit (for example, Memory > 4 GB vs Memory > 4096 MB) does not change the match. The unit is only a display convenience.
When you switch the field in the builder, the operator combo resets to a sensible default:
You can change to any compatible operator after picking the field.
Operators apply to a single condition. The logical operator that combines all conditions (AND or OR) is set once for the whole filter, not per condition. See Building a filter for how to switch it.